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[1]黎俊波,李楠楠,余响林*,等.高选择性铁离子荧光探针的合成及性质研究[J].武汉工程大学学报,2010,(05):11-14.[doi:10.3969/j.issn.16742869.2010.05.003]
　LI Jun bo,LI Nan nan,YU Xiang lin,et al.Synthesis and properties of the Fe3+ fluorescence probewith high selectivity[J].Journal of Wuhan Institute of Technology,2010,(05):11-14.[doi:10.3969/j.issn.16742869.2010.05.003]
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2010年05期
页码:
11-14
栏目:
材料科学与工程
出版日期:
2010-05-31

文章信息/Info

Title:
Synthesis and properties of the Fe3+ fluorescence probe
with high selectivity
文章编号:
16742869(2010)05001104
作者:
黎俊波; 李楠楠; 余响林*; 王俊; 曾艳
武汉工程大学绿色化工过程省部共建教育部重点实验室，湖北 武汉 430074
Author(s):
LI Junbo;  LI Nannan;  YU Xianglin;  WANG Jun; ZENG Yan
Key Laboratory for Green Chemical Process of Ministry of Education, Wuhan Institute of Technology, Wuhan 430074, China
关键词:
罗丹明; 铁离子; 检测
Keywords:
Rhodamine;  iron ions;  sensor
分类号:
O615.4+1
DOI:
10.3969/j.issn.16742869.2010.05.003
文献标志码:
A
摘要:
设计、合成了一种基于罗丹明染料的过渡金属离子荧光探针罗丹明衍生物2.在乙腈溶液中该探针本身无荧光，当向其中加入Fe3+后，在588 nm处产生强的荧光，而其它过渡金属离子除Zn2+和Pb2+有一定的荧光增强外，基本都无荧光增强现象，该化合物是一种高选择性的Fe3+荧光探针.
Abstract:
A novel fluorescence probe 2 has been designed and synthesized. The results showed that a significant enhancement of fluorescence at 588 nm was observed when Fe3+ was added to the CH3CN solution of the compound 2 which has no fluorescence originally. The addition of other transition metal ions showed no obvious enhancement of fluorescence, except for Zn2+ and Pb2+ with certain degree of enhancement. Therefore, compound 2 is a good Fe3+ fluorescence probe with high selectivity.

参考文献/References:

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［6］Xiang Y, Tong A. A new rhodaminebased chemosensor exhibiting selective Fe(III)amplified fluorescence ［J］.Org Lett, 2006, 8:15491552.
［7］Mao J, Wang L, Dou W, et al. Tuning the selectivity of two chemosensors to Fe(Ⅲ) and Cr(Ⅲ) ［J］. Org Lett, 2007, 9:45674570.
［8］Yuan M J, Zhou W D, Liu X F, et al. A multianalyte chemosensor on a single molecule: Promising structure for an integrated logic gate ［J］. J Org Chem, 2008, 73:50085014.
［9］Zheng H, Qian Z H, Xu L, et al.. Switching the recognition preference of rhodamine B spirolactam by replacing one atom: design of rhodamine B thiohydrazide for recognition of Hg(II) in aqueous solution ［J］. Org Lett, 2006, 8:859861.
［10］Huang K W, Yang H, Zhou Z G, et al. Multisignal chemosensor for Cr3+ and its application in bioimaging ［J］. Org Lett, 2008, 10:25572560.
［11］Shiraishi Y, Sumiya S, Kohno Y, et al. A rhodaminecyclen conjugate as a highly sensitive and selective fluorescent chemosensor for Hg(II) ［J］. J Org Chem, 2008, 73:85718574.

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备注/Memo

备注/Memo:
收稿日期：20100303基金项目：化工过程省部其建教育部重点实验室科研基金（No.RGCT200902,GCP200905）,武汉工程大学科学研究基金（No.10092012,No.10092021）作者简介：黎俊波(1979)，男，湖北监利人，博士，讲师，硕士研究生导师.研究方向：功能染料.
余响林（1980），女，湖北武汉人，博士，讲师，硕士研究生导师.研究方向：功能材料的合成与性能检测.
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