[1]王继科,王巧,陈金芳*,等.沼气常温氧化铁脱硫催化剂的研制[J].武汉工程大学学报,2010,(07):5-08.[doi:10.3969/j.issn.16742869.2010.07.002]
WANG Ji ke,WANG Qiao,CHEN Jin fang,et al.Rural household biogas desulfurization catalysts for iron oxide at room temperature[J].Journal of Wuhan Institute of Technology,2010,(07):5-08.[doi:10.3969/j.issn.16742869.2010.07.002]
点击复制
《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]
- 卷:
-
- 期数:
-
2010年07期
- 页码:
-
5-08
- 栏目:
-
化学与化学工程
- 出版日期:
-
2010-07-31
文章信息/Info
- Title:
-
Rural household biogas desulfurization catalysts for
iron oxide at room temperature
- 文章编号:
-
16742869(2010)07000504
- 作者:
-
王继科1; 王巧2; 陈金芳3*; 高路4
-
1.武汉工程大学科学技术处,湖北 武汉 430074;2.武汉工程大学化工与制药学院,湖北 武汉 430074;
3.武汉工程大学绿色化工过程省部共建教育部重点实验室,湖北 武汉 430074;
4.武汉工程大学湖北省新型反应器与绿色工艺重点实验室,湖北 武汉 430074
- Author(s):
-
WANG Jike1; WANG Qiao2; CHEN Jinfang3; GAO Lu4
-
1.Department of Science and Technology,Wuhan Institute of Technology,Wuhan 430074,China;
2.School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430074, China;
3.Hubei Novel Reactor & Green Chemical Technology Key Laboratory, Wuhan 430074, China
4.Key Laboratory for Green Chemical Process of Ministry of Education,Wuhan 430074, China
-
- 关键词:
-
清洁能源; 沼气; 硫化氢; 脱硫剂; 羟基氧化铁
- Keywords:
-
clean energy; biogas; hydrogen sulfide; desulfurizer; FeOOH
- 分类号:
-
TQ426.6
- DOI:
-
10.3969/j.issn.16742869.2010.07.002
- 文献标志码:
-
A
- 摘要:
-
以农村可再生能源—沼气的清洁、环保使用为背景,以最终产品脱硫剂无毒、无害为前提,以实现常温脱硫为目标,选用FeOOH为沼气中硫化氢的主体脱除剂,一种代号为M酸的物质为协同催化脱除剂,二水硫酸钙作为赋形成核剂设计了沼气常温氧化铁脱硫催化剂的配方、生产工艺.产品经检测达到使用要求.
- Abstract:
-
The rural renewable energybiogas clean, environmentally friendly desulfurization catalyst has been used as the background. With the final product nontoxic, harmless desulfurizer as a prerequisite. Desulfurization conditions have been achieved at room temperature as the target. FeOOH, the main removal of hydrogen sulfide gas agent in the experimental design has been selected. One kind of material, codenamed M acid was selected as the synergistic catalytic removal of agents. Calcium sulfate dihydrate was formed as a nucleating agent assigned to use. Gas under normal temperature conditions for the desulfurization of iron oxide desulfurization catalyst components of the quality of distribution was designed. The products have been proven by testing which meet requirements.
参考文献/References:
[1]邢同春.关于干式氢氧化铁脱硫的分析[J].煤气与热力,1990,10(6):1822.
[2]任爱玲, 阮宜纶.以工业废物制备高效氧化铁系脱硫剂的研究[J].环境工程,2000,18(4):4043.
[3]呼德龙,马凤美.关于氧化铁脱硫剂活性问题的探讨[J].煤气与热力,2000,20(2):126127.
[4]李彦旭,钟炳.氧化的脱硫剂高温煤气脱硫行为的研究:还原及硫化动力学[J].燃料化学学报,1998,26(2):130134.
[5]刘斐,房鼎业,石天宝.NT705型脱硫剂的本征动力学研究[J].化学工业与工程技术,2004,25(4):2124.
[6]高志华,阴丽华, 李春虎,等.纳米αFeOOH催化剂一段法脱除COS和H2S性能的研究[J].燃料化学学报,2003,31(3):249253.
[7]巩志坚, 田原宇,李文华,等.不同原料制备羟基氧化铁的晶型及脱硫活性研究[J].煤炭学报,2006,31(6):790793.
[8]刘振义,刘凤仁.一种高硫容氧化铁脱硫剂活性组分的表征[J].气体净化,2006,6(C00):107111.
[9]兰昌云, 何新秀, 徐海军,等.高效常温氧化铁脱硫剂的制备[J].天然气工业,2004,24(12):124126.
[10]沈凯.NCT型常温氧化铁脱硫剂的研制[J].南化科技,1993,14(3):1114.
[11] 王丽琴,王晓琪,马永强,等.纸带—光纤技术对硫化氢气体测量的初探[J].分析试验室,2002,21(4):4951.
[12]中华人民共和国国家标准. GB 12211-90城市燃气中硫化氢含量测定[S].北京:中国标准出版社,1991.
备注/Memo
- 备注/Memo:
-
张瑞收稿日期:20100520作者简介:王继科(1962),男,湖北麻城人,工程师.研究方向:化工医药和新能源.
*通信联系人:陈金芳,教授,硕士研究生导师.研究方向:化学工艺.
更新日期/Last Update: