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[1]刘安昌,夏强,张良,等.阳离子光固化活性单体氧杂环丁烷的合成[J].武汉工程大学学报,2010,(09):14-16.[doi:10.3969/j.issn.16742869.2010.09.004]
　LIU An chang,XIA Qiang,ZHANG Liang,et al.Synthesis of oxetanil for the cationic curing monomer[J].Journal of Wuhan Institute of Technology,2010,(09):14-16.[doi:10.3969/j.issn.16742869.2010.09.004]
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阳离子光固化活性单体氧杂环丁烷的合成(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2010年09期
页码:
14-16
栏目:
化学与化学工程
出版日期:
2010-09-30

文章信息/Info

Title:
Synthesis of oxetanil for the cationic curing monomer
文章编号:
16742869(2010)09001403
作者:
刘安昌; 夏强; 张良; 李高峰
武汉工程大学湖北省新型反应器与绿色化学工艺重点实验室,湖北 武汉 430074
Author(s):
LIU Anchang; XIA Qiang; ZHANG Liang; LI Gaofeng
Hubei Key Laboratory of Novel Reactor and Green Chemical Technology,Wuhan Institute of Technology,Wuhan 430074,China
关键词:
3; 3［氧基双亚甲基］双［3乙基］氧杂环丁烷; 3乙基3羟甲基氧杂环丁烷; 合成
Keywords:
 ; bis(1ethyl(3oxetanil)methyl)ether;  3ethyl3hydroxymethyloxetane;  synthesis
分类号:
O624
DOI:
10.3969/j.issn.16742869.2010.09.004
文献标志码:
A
摘要:
以三羟甲基丙烷和碳酸二乙酯为原料,经环化裂解生成3乙基3羟甲基氧杂环丁烷.然后经磺酰化,氯化得到3乙基3氯甲基氧杂环丁烷,在碱性条件下,四丁基溴化铵作相转移催化剂,3乙基3氯甲基氧杂环丁烷与3乙基3羟甲基氧杂环丁烷醚化得到目的产物3,3［氧基双亚甲基］双［3乙基］氧杂环丁烷.产物经红外光谱和核磁共振谱得到确证.
Abstract:
 3hydroxymethyl3ethyloxetane, which was synthesized from trihydroxymethylenepropane and diethyl carbonatereaction, reacted with methanesulfonylchloride in the present of triethylamine under the temperature of -10—15 ℃ to give 3ethyl3methanesulfonyloxymethyloxetane; followed by reaction with NaCl to give 3chloromethyl3ethyloxetane; Then in the presence of Bu4NBr as phasetransfer catalysts, 3chloromethyl3ethyloxetane reacted with 3hydroxymethyl3ethyloxetane to give bis(1ethyl(3oxetanil)methyl)ether. The structure of title compound was identified by IR and 1HNMR spectrum.

参考文献/References:

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备注/Memo

备注/Memo:
张瑞收稿日期:20090524作者简介:刘安昌(1964),男,江西吉安人,教授,博士.研究方向:精细有机合成.
更新日期/Last Update: