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[1]周寻,吴婧,陈高峰,等.含Fe3+层状类钙钛矿合成及其电化学性能[J].武汉工程大学学报,2010,(11):65-69.[doi:10.3969/j.issn.16742869.2010.11.017]
　ZHOU Xun,WU Jing,CHEN Gao feng,et al.Preparation and electrochemical performance of layered perovskite containing(Ⅲ)iron ion[J].Journal of Wuhan Institute of Technology,2010,(11):65-69.[doi:10.3969/j.issn.16742869.2010.11.017]
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含Fe3+层状类钙钛矿合成及其电化学性能
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2010年11期
页码:
65-69
栏目:
化学与化学工程
出版日期:
2010-11-30

文章信息/Info

Title:
Preparation and electrochemical performance of
layered perovskite containing(Ⅲ)iron ion
文章编号:
16742869(2010)11006505
作者:
周寻1; 吴婧2; 陈高峰1; 林志东1*
1.武汉工程大学等离子体化学与新材料省重点实验室,湖北 武汉 430074；
2.武汉理工大学材料复合新技术国家重点实验室,湖北 武汉 430070
Author(s):
ZHOU Xun1;  WU Jing2;  CHEN Gaofeng1;  LIN Zhidong1
1.Province Key Laboratory of Plasma Chemistry & Advanced Materials,
Wuhan Institute of Technology, Wuhan 430074,China;
2.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,
Wuhan University of Technology, Wuhan 430070, China
关键词:
层状类钙钛矿结构; 杂合物; 酚藏花红; 氧化还原; 电催化
Keywords:
layered perovskitetype structure;  hybrid;  phenosafranine;  oxidationreduction;  electroactivity
分类号:
TB33;O646
DOI:
10.3969/j.issn.16742869.2010.11.017
文献标志码:
A
摘要:
以酚藏花红为有机层、以含三价铁的Fe(CN)3-6为无机层,在空气中,合成层状有机无机类钙钛矿杂合物.利用扫描电镜(SEM)和X射线衍射(XRD)对其表面形貌和微观结构进行表征.利用循环伏安法研究了杂合物修饰碳糊电极的电化学性能,并探讨了NaNO2、NaBr、对苯二酚、盐酸羟胺与合成的杂合物相互作用.结果表明：合成的杂合物具有典型的层状结构,具有良好的电化学活性,可进一步电化学器件应用研究.
Abstract:
A steady layered organicinorganic perovskite hybrid containing Fe3+ was prepared in the air with phenosafranine as organic sheets, the Fe(CN)36 as inorganic sheets. The morphology and microstructure of hybrid were characterized by SEM and XRD. Electrochemical performances of carbon paste electrode modified by hybrid were investigated with cyclic voltammetry. The interactions between NaNO2, NaBr, hydroquinone, hydroxylamine hydrochloride with hybrid were studied. The results show that the structure of hybrid is typical layered perovskite type. The hybrid shows good electrochemical activity, and can be used as electrochemical materials.

参考文献/References:

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备注/Memo

备注/Memo:
龚晓宁收稿日期：20100701基金项目：国家自然科学基金(50803047)，博士后特别资助(200902460)，湖南大学化学计量及生物传感国家重点实验室开放基金(2008013)作者简介：周寻(1986)，男，湖北鄂州人，在读硕士.研究方向：有机无机杂化层状类钙钛矿结构材料及其传感器的研究.指导老师：林志东，男，教授，博士.研究方向：纳米材料
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