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[1]向丽,王燕,程健*,等.丙烯在甲醇-双氧水中的溶解度[J].武汉工程大学学报,2013,(10):23-27.[doi:103969/jissn16742869201310005]
　XIANG Li,WANG Yan,CHENG Jian,et al.Solubility of propylene in methanol\|hydrogen peroxide[J].Journal of Wuhan Institute of Technology,2013,(10):23-27.[doi:103969/jissn16742869201310005]
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丙烯在甲醇-双氧水中的溶解度(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2013年10期
页码:
23-27
栏目:
化学与化学工程
出版日期:
2013-11-10

文章信息/Info

Title:
Solubility of propylene in methanol\|hydrogen peroxide
文章编号:
16742869(2013)10002305
作者:
向丽1; 2; 3; 王燕2; 3; 程健2; 3*;  林民4; 朱斌4
1. 武汉工程大学邮电与信息工程学院，湖北 武汉 430074；2. 武汉工程大学绿色化工过程省部共建教育部重点实验室，湖北 武汉 430074；3. 武汉工程大学湖北省新型反应器与绿色化学工艺重点实验室，湖北 武汉 430074；4. 中国石油化工股份有限公司石油化工科学研究院，北京 100083
Author(s):
XIANG Li1; 2; 3;  WANG Yan2; 3; CHENG Jian2; 3; LIN Min4;  ZHU Bin4
1. The College of Post and Telecommunication of Wuhan Institute of Technology, Wuhan 430074, China; 2. Key Laboratory for Green Chemical Process of Ministry of Education, Wuhan Institute of Technology, Wuhan 430074, China; 3. Hubei Key Laboratory of Novel Chemical Reactor & Green Chemical Technology, Wuhan Institute of Technology, Wuhan 430074, China; 4. Research Institute of Petroleum Processing, China Petro\|Chemical Corporation, Beijing 100083, China
关键词:
丙烯; 环氧丙烷; 环氧化; 溶解度
Keywords:
propylene;  propylene oxide;  epoxidation;  solubility
分类号:
TQ221. 212; O642.42
DOI:
103969/jissn16742869201310005
文献标志码:
A
摘要:
钛硅分子筛催化丙烯环氧化是一条生产环氧丙烷的清洁工艺，其多相反应体系的相态研究是优化该反应体系的基础.利用可视相平衡仪在不同条件下测量了丙烯在甲醇\|双氧水中的溶解度.结果表明，体系温度、双氧水有效质量浓度和甲醇含量是影响丙烯溶解度的关键因素.在双氧水∶丙烯∶甲醇摩尔比一定、温度相同且体系均为气\|液\|液三相平衡的条件下，30%（质量分数）双氧水氧化体系甲醇相中丙烯的溶解度低于50%（质量分数）双氧水氧化体系.在双氧水有效含量不同的两种氧化体系中，当甲醇含量较低时，体系呈现为气\|液\|液三相平衡，在30~60 ℃范围内可通过升温提高丙烯的溶解度；提高甲醇含量到一定程度时，体系液相在较低的温度下即可呈均相，为丙烯环氧化提供良好的反应环境.
Abstract:
Catalytic propylene epoxidation on titanium silicon molecular sieve is a green process for production of propylene oxide, and the phase behavior of the multiphase reaction system is the foundation to optimize this reaction. Visual phase equilibrium apparatus was used for the propylene solubility measurement in methanol\|hydrogen peroxide under different conditions. The research results show that system temperature, hydrogen peroxide concentration (the mass fraction of H2O2 in hydrogen peroxide solution) and the methanol content are the key factors to the propylene solubility；the propylene solubility in hydrogen peroxide\|methanol of 30% hydrogen peroxide system is less than that of 50% hydrogen peroxide system when the 50% hydrogen peroxide system and 30% hydrogen peroxide system have the same materials molar ratio and the same system temperature, and both the two systems present a gas\|liquid\|liquid phase equilibrium system; moreover, for the hydrogen peroxide (50% or 30%)\|propylene\|methanol system, when the feed methanol content is low, the solubility of propylene is improved by raising the temperature with 30-60 ℃; while when the methanol content is higher enough, the system liquid phase could be experienced as homogeneous with high propylene solubility at lower temperature, which provides a good reaction circumstance for the epoxidation of propylene.

参考文献/References:

［1］刘民, 董毅, 郭新闻,等. 固定床反应器上TS\|1催化丙烯环氧化［J］. 石油学报(石油加工), 2010, 26(5): 677\|683.LIU Min,DONG Yi,GUO Xin\|wen,et al.Propylene Epoxidation over Modified TS\|1 Reactor ［J］. Acta Petrolei Sinica(Petroleum Processing Section),2010,26(5):677\|683. (in Chinese)［2］刘俊红. 环氧丙烷的生产现状以及消费概况［J］.化工中间体,2004(5): 37\|40.LIU Jun\|hong.Producing Present Situation and Consumption of Propylene Oxide (PO) ［J］.Chemical Intermediate,2004(5):37\|40.(in Chinese)［3］朱留琴. 环氧丙烷的生产技术及市场分析［J］. 精细石油化工进展, 2012, 13(10): 39\|43.ZHU Liu\|qin. Propylene Oxide Production Techniques and Analysis on Propylene Oxide Market ［J］. Advances in Fine Petrochemicals, 2012, 13(10): 39\|43. (in Chinese)［4］Forlin A, Tegon P, Paparatto G. Process for the continuous production of an olefinic oxide: US, 7138534［P］. 2006.［5］Serrano D P, Sanz R, Pizarro P, et al. Preparation of extruded catalysts based on TS\|1 zeolite for their application in propylene epoxidation ［J］. Catalysis Today, 2009, 143(1\|2): 151\|157.［6］李华,林民,王伟,等. 用丙烯双氧水环境友好法制备环氧丙烷的研究［J］. 化学推进剂与高分子材料, 2012, 10(3): 72\|74.LI Hua, LIN Min, WANG Wei, et al. Study on Preparation of Propylene Oxide by Environmental\|Friendly Propylene\|Hydrogen Peroxide Method ［J］. Chemical Propellants & Polymeric Materials, 2012, 10(3): 72\|74. (in Chinese)

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备注/Memo

备注/Memo:
收稿日期：20130822基金项目：石油化工催化材料与反应工程国家重点实验室开放课题资助作者简介：向丽（1983\|），女，湖北鄂州人，讲师，博士.研究方向：超临界流体技术研究.*通信联系人
更新日期/Last Update: 2013-11-11