|本期目录/Table of Contents|

[1]MATIOLO Elves,COUTO Hudson Jean?Bianquini,TEIXEIRA Michelle Fernanda de Lira,等.巴西磷矿泥浆中磷灰石的回收[J].武汉工程大学学报,2017,39(06):519-528.[doi:10. 3969/j. issn. 1674?2869. 2017. 06. 001]
 MATIOLO Elves,COUTO Hudson Jean Bianquini,TEIXEIRA Michelle Fernanda de Lira,et al.Recovery of Apatite from Slimes of A Brazilian Phosphate Ore[J].Journal of Wuhan Institute of Technology,2017,39(06):519-528.[doi:10. 3969/j. issn. 1674?2869. 2017. 06. 001]
点击复制

巴西磷矿泥浆中磷灰石的回收(/HTML)
分享到:

《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
39
期数:
2017年06期
页码:
519-528
栏目:
化学与化学工程
出版日期:
2017-12-30

文章信息/Info

Title:
Recovery of Apatite from Slimes of A Brazilian Phosphate Ore
文章编号:
20170601
作者:
MATIOLO Elves1COUTO Hudson Jean?Bianquini1TEIXEIRA Michelle Fernanda de Lira2FREITAS Amanda Soaresde1ALMEIDA Renata Nigride1
1. 矿物工艺学中心(CETEM/MCTIC),RJ21941-908,巴西;2. Copebras-CMOC公司,GO75701-970,巴西
Author(s):
MATIOLO Elves1COUTO Hudson Jean Bianquini1TEIXEIRA Michelle Fernanda de Lira2FREITAS Amanda Soares de1ALMEIDA Renata Nigri de1
1. Centro de Tecnologia Mineral (CETEM/MCTIC), RJ 21941-908, Brazil;2. Copebras- CMOC International, GO 75701-970, Brazil
关键词:
磷灰石浮选矿泥浮选柱
Keywords:
apatite flotation slimes column flotation
分类号:
TQ126.3
DOI:
10. 3969/j. issn. 1674?2869. 2017. 06. 001
文献标志码:
A
摘要:
针对我国严重匮乏可溶性钾盐资源,而非可溶性钾资源却非常丰富,如磷钾伴生矿,因而探索从磷钾伴生矿中提取可溶性钾具有重要意义. 本文强化了磷钾伴生矿的酸浸过程,研究了在HCl-CaF2体系下,表面活性剂对磷钾伴生矿中钾浸出的影响. 结果表明:阴离子表面活性剂可以强化钾的浸出,阳离子表面活性剂对钾的浸出未产生明显影响,非离子表面活性剂会抑制钾的浸出. 通过筛选得到较佳的表面活性剂为十二烷基硫酸钠(SDS),其添加量为1.25 g/L,与未添加SDS的相比,钾浸出率提高了约8.5%,达到了98.01%
Abstract:
In general terms, the flowsheet applied to apatite concentration in Brazilian phosphate industry plants involves grinding; classification in coarse and fines fractions; magnetic separation (low and high intensity); desliming to remove particles < 10 μm; barite flotation and apatite flotation. This work shows the results obtained in a study of apatite concentration from a slime sample provided by the industrial phosphate ore plant of the Copebras (China Molybdenum-CMOC International), located at Catalo (Goias state, Brazil). The feed sample containing 13.2% of P2O5; 14.0% of CaO; 19.7% of SiO2 and 27.7% of Fe2O3, which corresponds to 32% of apatite, 25% of goethite, quartz (18%) and gorceixite (5.2%). Particle size characterization showed that the characteristic diameters (D32, D10, D50 and D90) were respectively 2.6 μm, 1.0 μm, 5.7 μm and 25 μm. Considering the flowsheet with desliming in hydrocyclones (40 mm) in two stages, followed by apatite flotation in columns, it was obtained a final concentrate with 35.6% P2O5 and main impurities Fe2O3and SiO2 around 4.0% and 5.1% respectively. Taking into account the mass and metallurgical balances of the desliming and flotation, the overall mass recovery was around 11% and the P2O5 recovery was 30%.

参考文献/References:

References [1] GIBSON C E, KELEBEK S, AGHAMIRIAN M. Niobium oxide mineral flotation: a review of literature and the current state of industrial operations[J]. International Journal of Mineral Processing, 2015,137:82-97.[2] ARAUJO A C, VIANA P R M, PERES A E C. Reagents in iron ore flotation[J]. Minerals Engineering, 2005,18: 219-224.[3] ROCHA L, CAN?ADO R Z L, PERES A E C. Iron ore slimes flotation[J]. Minerals Engineering, 2010, 23:842-845.[4] THELLA J S, MUKHERJEE A K, SRIKAKULAPU N G. Processing of high alumina iron ore slimes using classification and flotation[J]. Powder Technology, 2012,217:418-426.[5] MATIOLO E,SOUZA A,RODRIGUES R T, et al. Treatment of a low grade compact itabirite iron ore from Carajás -Brazil[C]// In: XXVI International Mineral Processing Congress-IMPC, 2012, New Delhi, 2012: 3315-3323.[6] ZHANG P, BOGAN M. Recovery of phosphate from Florida beneficiation slimes I. Re-identifying the problem[J]. Minerals Engineering, 1995, 8 (4/5): 523-534.[7] GUIMAR?ES R C, PERES A E C. Experiência brasileira de produ??o de concentrado fosfático a partir de lamas[C]. Em: XIX Encontro Nacional de Tratamento de Minérios e Metalurgia Extrativa, Recife, Brasil, I,2002: 247-253 . (In Portuguese)[8] GUIMAR?ES R C, PERES A E C. Production of phosphate concentrates from slimes: Brazilian experience[C]// In: Proceedings XXII International Mineral ProcessingCongress, Cape-Town, South Africa, 2003: 606-612. [9] HERNINZ F, CALERO M, Blázquez G. Flotation of low-grade phosphate ore [J]. Advanced Powder Technology, 2004, 15( 4): 421-433. [10] TEAGUE A J, LOLLBACK M C. The beneficiation of ultrafine phosphate[J]. Minerals Engineering,2012, 27(28): 52-59. [11] SIVAMOHAN R. The problem of recovering very fine particles in mineral processing -a review[J]. International Journal of Mineral Processing,1990,28:247-288. [12] SUBRAHMANYAM T V, FORSSBERG E F S. Fine particle processing: shear flocculation and carrier flotation-a review [J]. International Journal of Mineral Processing, Amsterdam,1990,30(3/4):265-286. [13] SHAHBAZI B, REZAI B, JAVAD KOLEINI S M. Bubble-particle collision and attachment probability on fine particles flotation [J]. Chemical Engineering and Processing: Process Intensification,2010,49(6):622-627. [14] IPEK H, OZDAG H. An investigation into the enrichment of phosphate slime by column flotation [J]. Developments in Mineral Processing, 2000: C8a-1 - C8a-5. [15] GUIMARES RC, ARAUJO A C, PERES A E C. Reagents in igneous phosphate ores flotation [J]. Minerals Engineering , 2005,18: 199-204.[16] GUIMARES R C, PERES A E C. Interfering ions in the flotation of a phosphate ore in a batch column [J]. Minerals Engineering,1999, 12(7): 757-768. [17] SANTOS M A, SANTANA R C, ATADE C H, et al. Effect of ionic species on the performance of apatite flotation [J]. Separation and Purification Technology, 2010, 76(1):15-20.

相似文献/References:

[1]柏中能,张文学,李耀基,等.云南海口中品位磷矿浮选产业化开发[J].武汉工程大学学报,2008,(02):9.
 BAI Zhong neng,ZHANG Wen xue,LI Yao ji,et al.The industrialization exploitation of the flotation ofmiddle grade phosphate in Yunnan Haikou[J].Journal of Wuhan Institute of Technology,2008,(06):9.
[2]杨文.铅锌矿石中有价金属的综合回收[J].武汉工程大学学报,2010,(05):57.[doi:10.3969/j.issn.16742869.2010.05.016]
 YANG Wen.Comprehensive recovery of valuable metal from LeadZinc ore[J].Journal of Wuhan Institute of Technology,2010,(06):57.[doi:10.3969/j.issn.16742869.2010.05.016]
[3]黄齐茂,黄晶晶,王巍,等.湖北某胶磷矿粗选工艺的优化[J].武汉工程大学学报,2011,(02):17.[doi:10.3969/j.issn.16742869.2011.02.004]
 HUANG Jing jing,HUANG Qi mao,WAN Wei,et al.Optimization of roughing technics for a certain collophanite from Hubei[J].Journal of Wuhan Institute of Technology,2011,(06):17.[doi:10.3969/j.issn.16742869.2011.02.004]
[4]李文洁,刘星,魏以和*.燃烧法测定捕收剂油酸钠的方法[J].武汉工程大学学报,2011,(02):25.[doi:10.3969/j.issn.16742869.2011.02.006]
 LI Wen jie,LIU Xing,WEI Yi he.Combustion method to quantitatively determine collector sodium oleate adsorbed on minerals[J].Journal of Wuhan Institute of Technology,2011,(06):25.[doi:10.3969/j.issn.16742869.2011.02.006]
[5]陈云峰,黄齐茂,潘志权*.磷矿浮选捕收剂的研究进展[J].武汉工程大学学报,2011,(02):76.[doi:10.3969/j.issn.1674]
 CHEN Yun feng,HUANG Qi mao,PAN Zhi quan.Progress of flotation collectors for phosphorus ores[J].Journal of Wuhan Institute of Technology,2011,(06):76.[doi:10.3969/j.issn.1674]
[6]魏祥松.我国内生和变质磷矿分布特点及选矿技术[J].武汉工程大学学报,2011,(02):83.[doi:10.3969/j.issn.16742869.2011.02.023]
 WEN Xiang song.Distribution characteristics and beneficiation of endogenetic and metamorphic phosphate ores in China[J].Journal of Wuhan Institute of Technology,2011,(06):83.[doi:10.3969/j.issn.16742869.2011.02.023]
[7]罗廉明,刘鑫.磷矿中MgO的赋存状态与其浮选脱除的关系[J].武汉工程大学学报,2011,(03):20.[doi:10.3969/j.issn.16742869.2011.03.006]
 LUO Lian ming,LIU Xin.Relations between MgO occurrence of phosphorite and its removal by flotation process[J].Journal of Wuhan Institute of Technology,2011,(06):20.[doi:10.3969/j.issn.16742869.2011.03.006]
[8]刘安,刘丽芬,罗惠华,等.安徽宿松磷矿低温浮选研究[J].武汉工程大学学报,2011,(03):26.[doi:10.3969/j.issn.16742869.2011.03.007]
 LIU An,LIU Li fen,LUO Hui hua,et al.Study on flotation of Anhui Susong phosphate rock at low temperature[J].Journal of Wuhan Institute of Technology,2011,(06):26.[doi:10.3969/j.issn.16742869.2011.03.007]
[9]戴新宇,于克旭,李红玲,等.北方某低品位磷矿选矿试验[J].武汉工程大学学报,2011,(03):56.[doi:10.3969/j.issn.16742869.2011.03.016]
 DAI Xin yu,YU Ke xu,LI Hong ling,et al.Experimental research on separating a phosphorus ore in North[J].Journal of Wuhan Institute of Technology,2011,(06):56.[doi:10.3969/j.issn.16742869.2011.03.016]
[10]吴艳妮,魏祥松,陈南华,等.北方低品位磷矿浮选捕收剂的研制与应用[J].武汉工程大学学报,2011,(03):59.[doi:10.3969/j.issn.16742869.2011.03.017]
 WU Yan ni,WEI Xiang song,CHEN Nan hua,et al.Development and application of flotation process collector for north lowgrade phosphate ore[J].Journal of Wuhan Institute of Technology,2011,(06):59.[doi:10.3969/j.issn.16742869.2011.03.017]
[11]杨勇,朱孔金,钱押林.辽宁某磁选尾矿回收磷灰石浮选试验[J].武汉工程大学学报,2011,(03):53.[doi:10.3969/j.issn.16742869.2011.03.015]
 YANG Yong,ZHU Kong jin,QIAN Ya lin.Study on flotation process reclaiming phosphor from magnetic tailings in Liaoning[J].Journal of Wuhan Institute of Technology,2011,(06):53.[doi:10.3969/j.issn.16742869.2011.03.015]

备注/Memo

备注/Memo:
The authors would like to thanks the Brazilian Institutes supporting this research, namely CNPq and CETEM/MCTIC. Special thanks to Copebras (CMOC International) for financial support and the permision for published this work. Acknowledgment to process technician, Mr. Fabio Novaes for his support during the experimental work.
更新日期/Last Update: 2018-01-04