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[1]李　亮,王浩楠,陈郁勃,等.聚吡咯/磺化石墨烯/磺化碳纳米管复合材料的界面合成[J].武汉工程大学学报,2020,42(01):45-49.[doi:10.19843/j.cnki.CN42-1779/TQ.201812007]
　LI Liang,WANG Haonan,CHEN Yubo,et al.Interfacial Synthesis and Properties of Polypyrrole/Sulfolated Graphene/Sulfolated Carbon Nanotubes Composites[J].Journal of Wuhan Institute of Technology,2020,42(01):45-49.[doi:10.19843/j.cnki.CN42-1779/TQ.201812007]
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
42
期数:
2020年01期
页码:
45-49
栏目:
材料科学与工程
出版日期:
2021-01-25

文章信息/Info

Title:
Interfacial Synthesis and Properties of Polypyrrole/Sulfolated Graphene/Sulfolated Carbon Nanotubes Composites
文章编号:
1674 - 2869（2020）01 - 0045 - 05
作者:
李　亮; 王浩楠; 陈郁勃; 陈宇欣; 喻湘华
武汉工程大学材料科学与工程学院，湖北 武汉 430205
Author(s):
LI Liang; WANG Haonan; CHEN Yubo; CHEN Yuxin; YU Xianghua
School of Materials Science and Engineering，Wuhan Institute of Technology， Wuhan 430205， China
关键词:
聚吡咯; 磺化石墨烯; 磺化碳纳米管; 复合材料; 界面聚合
Keywords:
polypyrrole;  sulfonated graphene;  sulfonated carbon nanotube;  composites;  interfacial polymerization
分类号:
O633
DOI:
10.19843/j.cnki.CN42-1779/TQ.201812007
文献标志码:
A
摘要:
对氧化石墨烯（GO）和碳纳米管（CNT）进行磺化处理，得到的磺化石墨烯（SG）和磺化碳纳米管（SCNT）在溶液中有良好的分散性。将SG、SCNT和氧化剂溶于水中形成水相，聚吡咯（PPy）单体溶于有机溶剂中形成有机相。有机相与水相之间发生界面反应，得到PPy/SG/SCNT复合材料。采用扫描电子显微镜、X射线衍射、电化学工作站对复合材料进行表征与测试。结果表明：PPy/SG/SCNT复合材料组分复合均匀，是无定形材料，其电化学性能较单独的PPy、SG或SCNT更优越，而且当正己烷作为有机溶剂时，所得到的三组分复合材料更适合作为超级电容器电极材料。
Abstract:
The graphene oxide（GO） and carbon nanotubes （CNT） were sulfonted to produce the sulfonated graphene （SG） and sulfonated carbon nanotube （SCNT）. SG and SCNT had good dispersion properties in solution. SG，SCNT and oxidizer were dissolved in water to form aqueous phase, and polypyrrole monomer（PPy） was dissolved in organic solvent to form organic phase. The PPy/SG/SCNT composite was obtained through the interfacial reaction between aqueous phase and organic phase. The composites were characterized by scanning electron microscopy，X-ray diffraction and electrochemical workstation. The results show that the amorphous PPy/SG/SCNT composites have uniform microstructure. Their electrochemical performances are superior to those of PPy，SG or SCNT. Moreover，when hexane is used as an organic solvent，the prepared composites are suitable electrode material used in supercapacitor.

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备注/Memo

备注/Memo:
收稿日期：2018-12-10 基金项目：武汉工程大学第十届研究生教育创新基金（CX2018062）；湖北高等学校省级大学生创新创业训练计划项目（201810490010） 作者简介：李　亮，博士，教授。E-mail： [email protected] 引文格式：李亮，王浩楠，陈郁勃，等. 聚吡咯/磺化石墨烯/磺化碳纳米管复合材料的界面合成［J］. 武汉工程大学学报，2020，42（1）：45-49.
更新日期/Last Update: 2020-06-09