|本期目录/Table of Contents|

[1]李 明,方旭东,曾小平,等.聚砜超滤膜的亲水改性及其性能研究[J].武汉工程大学学报,2020,42(06):642-646.[doi:10.19843/j.cnki.CN42-1779/TQ.202006006]
 LI Ming,FANG Xudong,ZENG Xiaoping,et al.Hydrophilic Modification and Performances of Polysulfone Ultrafiltration Membrane[J].Journal of Wuhan Institute of Technology,2020,42(06):642-646.[doi:10.19843/j.cnki.CN42-1779/TQ.202006006]
点击复制

聚砜超滤膜的亲水改性及其性能研究(/HTML)
分享到:

《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
42
期数:
2020年06期
页码:
642-646
栏目:
材料科学与工程
出版日期:
2021-01-30

文章信息/Info

Title:
Hydrophilic Modification and Performances of Polysulfone Ultrafiltration Membrane
文章编号:
1674 - 2869(2020)06 - 0642 - 05
作者:
李 明方旭东曾小平王大威张 勇吴江渝*
武汉工程大学材料科学与工程学院,湖北 武汉 430205
Author(s):
LI MingFANG XudongZENG XiaopingWANG DaweiZHANG YongWU Jiangyu*
School of Materials Science and Engineering,Wuhan Institute of Technology,Wuhan 430205,China
关键词:
超滤膜亲水性埃洛石聚砜
Keywords:
ultrafiltration membranehydrophilicityhalloysitepolysulfone
分类号:
TQ319
DOI:
10.19843/j.cnki.CN42-1779/TQ.202006006
文献标志码:
A
摘要:
以聚砜、聚乙烯吡咯烷酮和多巴胺修饰的埃洛石纳米管为主要原料,通过相转化法制备改性聚砜超滤膜。利用扫描电子显微镜、接触角测量仪、通量测试仪对滤膜进行结构及性能表征,交替过滤纯水与牛血清蛋白溶液测试改性超滤膜的循环稳定性。结果表明:改性埃洛石的掺入提高了超滤膜的水通量与截留率,改性后超滤膜水接触角从85.2°下降到67.4°,当改性埃洛石质量分数为1.0%时,超滤膜的纯水通量达到最大值440 L m-2 h-1,截留率从60%上升到92%。连续过滤200 min后,水通量最大值为400 L m-2 h-1
Abstract:
A modified polysulfone ultrafiltration membrane was prepared by phase inversion,with polysulfone,polyvinylpyrrolidone,and dopamine-modified halloysite nanotubes as the main raw materials. The structure and performance of the prepared membrane were characterized by scanning electron microscopy,contact angle measuring instrument, flux test divice. The cycling stability of the modified ultrafiltration membrane was also investigated by alternate filtration of pure water and bovine serum protein solution. The results show that the addition of modified halloysite nanotubes improves the water flux and retention rate of the ultrafiltration membrane. After modification,the water contact angle of the ultrafiltration membrane drops from 85.2° to 67.4°. The pure water flux of the ultrafiltration membrane reaches the maximum value of 440 L m-2 h-1,and the rejection rate increases from 60% to 92% when the mass fraction of modified halloysite nanotubes is 1.0%. After the filtration for 200 min, the maximum water flux is 400 L m-2 h-1.

参考文献/References:

[1] SCHWARZENBACH R P,EGLI T,HOFSTETTER T B,et al. Global water pollution and human health [J]. Annual Review of Environment and Resources,2010,35(1):109-136. [2] YE C C,AN Q F,WU J K,et al. Nanofiltration membranes consisting of quaternized polyelectrolyte complex nanoparticles for heavy metal removal [J]. Chemical Engineering Journal,2019,359:994-1005. [3] RAZI F,MULYATI S,ARAHMAN N. The performance of bovine serum albumin filtration by using polyethersulfone-Tetronic 304 blend ultrafiltration membrane [J]. F1000 Research,2019,8:953:1-12. [4] 童利文. 聚砜-聚酰胺复合纳滤膜的制备与表征[D]. 武汉:武汉工程大学,2016. [5] YOU S H,TSENG D H,HSU W C. Effect and mechanism of ultrafiltration membrane fouling removal by ozonation [J]. Desalination,2007,202(1/2/3):224-230. [6] JIM K J,FANE A G,FELL C J D,et al. Fouling mechanisms of membranes during protein ultrafiltration [J]. Journal of Membrane Science,1992,68(1/2):79-91. [7] 谢荣华. 聚氯乙烯超滤膜亲水性改性及水过滤性能研究[D]. 哈尔滨:哈尔滨工程大学,2010. [8] LIU S B,WANG Z,SONG P. Free radical graft copolymerization strategy to prepare catechin modified chitosan loose nanofiltration (NF) membrane for dye desalination [J]. ACS Sustainable Chemistry & Engineering,2018,6(3):4253-4263. [9] GANCARZ I,PO[Z] NIAK G,BRYJAK M. Modification of polysulfone membranes:3. Effect of nitrogen plasma [J]. European Polymer Journal,2000,36(8):1563-1569. [10] KASEMSET S,WANG L,HE Z W,et al. Influence of polydopamine deposition conditions on hydraulic permeability,sieving coefficients,pore size and pore size distribution for a polysulfone ultrafiltration membrane [J]. Journal of Membrane Science,2017,522:100-115. [11] MILLER D J,DREYER D R,BIELAWSKI C W,et al. Surface modification of water purification membranes [J]. Angewandte Chemie International Edition,2017,56(17):4662-4711. [12] KIM K S,LEE K H,CHO K,et al. Surface modification of polysulfone ultrafiltration by oxygen plasma treatment [J]. Journal of Membrane Science,2002,199(1/2):135-145. [13] QIAO X L,ZHANG Z J,PING Z H. Hydrophilic modification of ultrafiltration membranes and their application in Salvia Miltiorrhiza decoction [J]. Separation and Purification Technology,2007,56(3):265-269. [14] XU Z Z,LIAO J Y,TANG H,et al. Antifouling polysulfone ultrafiltration membranes with pendent sulfonamide groups [J]. Journal of Membrane Science,2018,548:481-489. [15] DU M L,GUO B C,JIA D M. Newly emerging applications of halloysite nanotubes [J]. Polymer International,2010,59(5):574-582. [16] 张芷铭,邢瑞思,吴洪. 埃洛石纳米管掺杂海藻酸复合膜制备及其渗透蒸发脱水研究[J]. 膜科学与技术,2020,40(1):45-52. [17] SHU Z,CHEN Y,ZHOU J,et al. Preparation of halloysite-derived mesoporous silica nanotube with enlarged specific surface area for enhanced dye adsorption [J]. Applied Clay Science,2016,132/133:114-121. [18] YUAN P,SOUTHON P D,LIU Z W,et al. Functionali- zation of halloysite clay nanotubes by grafting with gamma-aminopropyltriethoxysilane [J]. Journal of Physical Chemistry C,2008,112(40):15742-15751. [19] RABIEE H, DAVOOD ABADI FARAHANI M H,VATANPOUR V. Preparation and characterization of emulsion poly(vinyl chloride) (EPVC)/TiO2 nano- composite ultrafiltration membrane [J]. Journal of Membrane Science,2014,472:185-193. [20] LI J F,XU Z L,YANG H,et al. Effect of TiO2 nanoparticles on the surface morphology and performance of microporous membrane [J]. Applied Surface Science,2009,255(9):4725-4732.

相似文献/References:

备注/Memo

备注/Memo:
收稿日期:2020-06-12基金项目:青海省科技厅重点研发与成果转化类(2020-GX-103)作者简介:李 明,硕士研究生。E-mail:[email protected]*通讯作者:吴江渝,博士,教授。E-mail:[email protected]引文格式:李明,方旭东,曾小平,等. 聚砜超滤膜的亲水改性及其性能研究[J]. 武汉工程大学学报,2020,42(6):642-646.
更新日期/Last Update: 2020-12-17