|本期目录/Table of Contents|

[1]柴 宽,高 佳,李小刚,等.钛酸钾晶须改性偏高岭土基多孔地质聚合物的制备与性能[J].武汉工程大学学报,2021,43(02):158-164.[doi:10.19843/j.cnki.CN42-1779/TQ.202106005]
 CHAI Kuan,GAO Jia,LI Xiaogang,et al.Preparation and Properties of Metakaolin Based Porous Geopolymer Modified by Potassium Titanate Whisker[J].Journal of Wuhan Institute of Technology,2021,43(02):158-164.[doi:10.19843/j.cnki.CN42-1779/TQ.202106005]
点击复制

钛酸钾晶须改性偏高岭土基多孔地质聚合物的制备与性能(/HTML)
分享到:

《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
43
期数:
2021年02期
页码:
158-164
栏目:
材料科学与工程
出版日期:
2021-04-30

文章信息/Info

Title:
Preparation and Properties of Metakaolin Based Porous Geopolymer Modified by Potassium Titanate Whisker
文章编号:
1674 - 2869(2022)02 - 0158 - 07
作者:
柴 宽1高 佳1李小刚2王相元3蔡 璐1吴艳光*1张云飞1
1. 武汉工程大学材料科学与工程学院,湖北 武汉 430205;2. 北京蓝色星球低碳科技有限公司,北京 100053;3. 北京安联国科科技咨询有限公司,北京 101312
Author(s):
CHAI Kuan1GAO Jia1LI Xiaogang2WANG Xiangyuan3CAI Lu1WU Yanguang*1ZHANG Yunfei1
1. School of Materials Science and Engineering,Wuhan Institute of Technology, Wuhan 430205, China;2. Beijing Blue Planet Low Carbon Technology Co.,Ltd, Beijing 100053, China;3. Beijing Allianz Technology Consulting Co.,Ltd, Beijing 101312, China
关键词:
地质聚合物钛酸钾晶须抗压强度孔隙率导热系数
Keywords:
geopolymerpotassium titanate whiskercompressive strengthporositycoefficient of thermal conductivity
分类号:
TU528
DOI:
10.19843/j.cnki.CN42-1779/TQ.202106005
文献标志码:
A
摘要:
为提高多孔地质聚合物的力学强度和隔热性能,分别以双氧水(H2O2)和十二烷基硫酸钠(SDS)为发泡剂和稳泡剂,采用化学发泡法制备了由钛酸钾晶须改性的偏高岭土基多孔地质聚合物材料,对其进行了微观结构表征及性能测试。结果表明,当发泡剂和稳泡剂质量分数分别为2.0%和1.5%时,孔结构分布均匀,总孔隙率最高可达51.6%,平均孔径为0.87 mm,其抗压强度为3.63 MPa;随着钛酸钾晶须质量分数从0.0%增至10.0%时,其最高抗压强度可达4.11 MPa。在钛酸钾晶须质量分数为20%时,其最低导热系数可达0.048 W/(m?K),相比于空白样,抗压强度提高了13.22%,导热系数降低了80.80%。钛酸钾晶须的引入可以明显提高多孔地质聚合物的抗压强度和隔热性能。
Abstract:
To improve the mechanical strength and thermal insulation performance of porous geopolymer,the metakaolin based porous geopolymer material modified by potassium titanate whisker was prepared by chemical foaming method with hydrogen peroxide and sodium dodecyl sulfate as foaming agent and stabilizing agent respectively, and its microstructure and properties were characterized. The results show that when the mass fractions of foaming agent and foaming stabilizer are 2.0% and 1.5%,respectively,the pore structure is evenly distributed,the total porosity is up to 51.6%,the average pore diameter is 0.87 mm,and the compressive strength is 3.63 MPa;When the mass fraction of potassium titanate whisker increases from 0.0% to 10.0%,its maximum compressive strength can reach 4.11 MPa. When the mass fraction of potassium titanate whisker is 20%,the lowest thermal conductivity can reach 0.048 W/(m?K). Compared with the blank sample,the compressive strength increases by 13.22% while the thermal conductivity decreases by 80.80%. It is demonstrated that the introduction of potassium titanate whisker can significantly improve the compressive strength and thermal insulation performance of porous geopolymer.

参考文献/References:

[1] SINGH B,ISHWARYA G,GUPTA M,et al. Geopolymer concrete:a review of some recent developments [J]. Construction and Building Materials,2015,85:78-90.[2] KITNASAMY D,PASUPATHY K,RAMAKRISHNAN S,et al. Progress,current thinking and challenges in geopolymer foam concrete technology [J]. Cement and Concrete Composites,2021,116(7):103886:1-17.[3] GU G H, XU F, HUANG X M, et al. Foamed geopolymer:the relationship between rheological properties of geopolymer paste and pore-formation mechanism[J]. Journal of Cleaner Production,2020,277:123238:1-13.[4] MASTALI M,KINNUNEN P,ISOMOISIO H,et al. Mechanical and acoustic properties of fiber-reinforced alkali-activated slag foam concretes containing lightweight structural aggregates [J]. Construction and Building Materials,2018,187:371-381.[5] WANG S,LI H Q,ZOU S,et al. Experimental research on a feasible rice husk/geopolymer foam building insulation material [J]. Energy and Buildings,2020,226:110358:1-12.[6] PASUPATHY K, RAMAKRISHNAN S,SANJAYAN J. Enhancing the mechanical and thermal properties of aerated geopolymer concrete using porous lightweight aggregates [J]. Construction and Building Materials,2020,264:120713:1-10.[7] HENON J,ALZINA A,ABSI J,et al. Porosity control of cold consolidated geomaterial foam:temperature effect [J]. Ceramics International,2012,38(1):77-84.[8] MCLELLAN B C, WILLIAMS R P, LAY J, et al. Costs and carbon emissions for geopolymer pastes in comparison to ordinary portland cement [J]. Journal of Cleaner Production,2011,19(9/10):1080-1090.[9] ZHANG Z H,PROVIS J L,REID A,et al. Geopolymer foam concrete:an emerging material for sustainable construction [J]. Construction and Building Materials,2014,56:113-127.[10] LI Y,ZHANG X G,CUI Y X,et al. Anti-corrosion enhancement of superhydrophobic coating utilizing oxygen vacancy modified potassium titanate whisker [J]. Chemical Engineering Journal,2019,374:1326-1336.[11] KORAT L, DUCMAN V. The influence of the stabilizing agent SDS on porosity development in alkali-activated fly-ash based foams [J]. Cement & Concrete Composites,2017,80:168-174.[12] JI Z H,LI M,SU L Y,et al. Porosity,mechanical strength and structure of waste-based geopolymer foams by different stabilizing agents [J]. Construction and Building Materials,2020,258:119555:1-10.[13] LI M H,LIU H,WANG Z F,et al. Facile synthesis of potassium hexatitanate whiskers by calcination at low temperature [J]. Journal of the Australian Ceramic Society,2020,56(3):859-865.[14] ALVAREZ-AYUSO E, QUEROL X,PLANA F,et al. Environmental,physical and structural characterisation of geopolymer matrixes synthesised from coal (co-)combustion fly ashes [J]. Journal of Hazardous Materials,2008,154(1/2/3):175-183.

相似文献/References:

[1]谢岁岁,饶 曦,张 芳,等.增强型地质聚合物的制备[J].武汉工程大学学报,2016,38(05):458.[doi:10. 3969/j. issn. 1674?2869. 2016. 05. 009]
 XIE Suisui,RAO Xi,ZHANG Fang,et al.Preparation of Reinforced Geopolymer[J].Journal of Wuhan Institute of Technology,2016,38(02):458.[doi:10. 3969/j. issn. 1674?2869. 2016. 05. 009]
[2]高巧玲,范功端*.硅灰对新型地质聚合物胶凝材料力学性能影响的研究进展[J].武汉工程大学学报,2020,42(05):540.[doi:10.19843/j.cnki.CN42-1779/TQ.202004008]
 GAO Qiaoling,FAN Gongduan*.Effects of Silica Fume on Mechanical Properties of Novel Geopolymer-Based Cementitious Materials: a Brief Review[J].Journal of Wuhan Institute of Technology,2020,42(02):540.[doi:10.19843/j.cnki.CN42-1779/TQ.202004008]
[3]鲁博文,羿庄城,吴艳光*,等.几种填料对偏高岭土-粉煤灰基地质聚合物的增强改性[J].武汉工程大学学报,2020,42(03):293.[doi:10.19843/j.cnki.CN42-1779/TQ.201909013]
 LU Bowen,YI Zhuangcheng,WU Yanguang*,et al.Reinforcement and Modification of Metakaolin-Fly Ash Based Geopolymer with Several Fillers[J].Journal of Wuhan Institute of Technology,2020,42(02):293.[doi:10.19843/j.cnki.CN42-1779/TQ.201909013]

备注/Memo

备注/Memo:
收稿日期:2021-06-07基金项目:湖北省自然科学基金(2020CFB649)作者简介:柴 宽,硕士研究生。E-mail:[email protected]*通讯作者:吴艳光,博士,副教授。E-mail:[email protected]引文格式:柴宽,高佳,李小刚,等. 钛酸钾晶须改性偏高岭土基多孔地质聚合物的制备与性能[J]. 武汉工程大学学报,2022,44(2):158-164.
更新日期/Last Update: 2022-04-28