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[1]焦 阳,骆怡欣,尹吉鑫,等.胺类环氧树脂固化剂改性研究进展[J].武汉工程大学学报,2023,45(03):251-255.[doi:10.19843/j.cnki.CN42-1779/TQ.202104025]
　JIAO Yang,LUO Yixin,YIN Jixin,et al.Progress in Modification of Amino-Containing Curing Agents for Epoxy Resins[J].Journal of Wuhan Institute of Technology,2023,45(03):251-255.[doi:10.19843/j.cnki.CN42-1779/TQ.202104025]
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胺类环氧树脂固化剂改性研究进展(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
45
期数:
2023年03期
页码:
251-255
栏目:
综述
出版日期:
2023-06-30

文章信息/Info

Title:
Progress in Modification of Amino-Containing Curing Agents for Epoxy Resins
文章编号:
1674 - 2869（2023）03 - 0251 - 05
作者:
焦 阳; 骆怡欣; 尹吉鑫; 吴江渝*
武汉工程大学材料科学与工程学院，等离子体化学与新材料湖北省重点实验室（武汉工程大学），
湖北 武汉 430205

Author(s):
JIAO Yang; LUO Yixin;  YIN Jixin; WU Jiangyu*
School of Materials Science and Engineering，Wuhan Institute of Technology； Hubei Key Laboratory of Plasma Chemistry and Advanced Materials（Wuhan Institute of Technology），Wuhan 430205，China
关键词:
环氧树脂; 胺类固化剂; 力学性能; 耐热性; 阻燃性
Keywords:
epoxy resin; amino-containing curing agent; mechanical properties; heat resistance; flame retardancy
分类号:
TQ314.256
DOI:
10.19843/j.cnki.CN42-1779/TQ.202104025
文献标志码:
A
摘要:
鉴于使用传统固化剂制备的环氧树脂材料存在力学性能及热性能不佳的问题，使用改性胺类固化剂，可以有效提升环氧树脂体系的综合性能。本文重点对改性胺类固化剂结构及树脂性能提升机理等方面进行了阐述。使用树枝状结构固化剂可以有效提高环氧树脂体系力学性能尤其是树脂韧性；使用苯环改性的固化剂可以很好地提升环氧树脂体系耐热性；而将杂原子改性固化剂引入环氧树脂体系后，树脂在阻燃性大幅提升的同时依旧可以保持较好的力学强度。最后，结合当前环氧树脂使用中的实际问题，对胺类固化剂今后的研究方向进行了展望。

Abstract:
The epoxy resin materials prepared with traditional curing agent have problems of poor mechanical and thermal properties. The comprehensive properties of epoxy resin system can be effectively improved by using amine-modified curing agents. Based on the performance improvement of epoxy resin，the structure of amine-modified curing agent and the mechanism of resin performance improvement were explored. The use of dendritic structure curing agent can effectively improve the mechanical properties of epoxy resin systems，especially the toughness of resin. The heat resistance of epoxy resin system can be improved by using benzene-modified curing agent. After introducing heteratomic-modified curing agent into the epoxy resin system，the resin can still maintain good mechanical strength while the flame retardancy is greatly improved. Finally，the research direction of amine-containing curing agent in the future is speculated based on the practical problems in the application of epoxy resin.

参考文献/References:

［1］ HE P，WANG J X，LU F Y，et al. Synergistic effect of polyaniline grafted basalt plates for enhanced corrosion protective performance of epoxy coatings ［J］. Progress in Organic Coatings，2017，110：1-9.

［2］ ZHANG Z Y，ZHANG W H，LI D S，et al. Mechanical and anticorrosive properties of graphene/epoxy resin composites coating prepared by in-situ method［J］.International Journal of Molecular Sciences，2015，16（1）：2239-2251.
［3］ YAPHARY Y L，YU Z C，LAM R H W，et al. Molecular dynamics simulations on adhesion of epoxy-silica interface in salt environment ［J］. Composites Part B： Engineering，2017，131：165-172.
［4］ GU J W， DONG W C， XU S， et al. Development of wave-transparent，light-weight composites combined with superior dielectric performance and desirable thermal stabilities ［J］. Composites Science & Technology，2017，144：185-192.
［5］ LUO S B， SHEN Y B，YU S H， et al. Construction of 3D-BaTiO3 network leading to significantly enhanced dielectric permittivity and energy storage density of polymer composites ［J］. Energy & Environmental Science，2017，10（1）：137-144.
［6］ 陈杰，马春柳，刘邦，等.热固性树脂及其固化剂的研究进展［J］.塑料科技，2019，47（2）：95-102.
［7］ KAMINSKAS L M，MCLEOD V M，PORTER C J H，et al. Association of chemotherapeutic drugs with dendrimer nanocarriers：an assessment of the merits of covalent conjugation compared to noncovalent encapsulation ［J］. Molecular Pharmaceutics，2012，9（3）：355-373.
［8］ WAN J T， LI C，BU Z Y， et al. Acrylonitrile-capped poly(propyleneimine) dendrimer curing agent for epoxy resins： model-free isoconversional curing kinetics，thermal decomposition and mechanical properties ［J］. Materials Chemistry and Physics，2013，138（1）：303-312.
［9］ CHENG Y Y， XU T W， HE P S. Polyamidoamine dendrimers as curing agents：the optimum polyamidoamine concentration selected by dynamic torsional vibration method and thermogravimetric analyses ［J］. Journal of Applied Polymer Science，2007，103（3）：1430-1434.
［10］ XU D M ， ZHANG K D， ZHU X L. Curing of DGEBA epoxy resin by low generation amino-group-terminated dendrimers ［J］. Journal of Applied Polymer Science，2006，101（6）：3902-3906.
［11］ WAN J T， LI C， FAN H， et al. Branched 1,6-diaminohexane-derived aliphatic polyamine as curing agent for epoxy：isothermal cure，network structure，and mechanical properties ［J］. Industrial & Engineering Chemistry Research，2017，56（17）：4938-4948.
［12］ MA C， QIU S L， YU B， et al. Economical and environment-friendly synthesis of a novel hyperbranched poly(aminomethylphosphine oxide-amine) as co-curing agent for simultaneous improvement of fire safety，glass transition temperature and toughness of epoxy resins ［J］. Chemical Engineering Journal，2017，322：618-631.
［13］ LU X D， HUANG Y D， ZHANG C H. Curing behavior and heat resistance of epoxy resin cured by diamine with heterocyclic ring ［J］. Journal of Reinforced Plastics & Composites，2007，26（16）：1713-1723.
［14］ REN H，TANG S C，SYED J A，et al. A naphthyl-imide-based epoxy resin：cure kinetics and application in carbon fiber reinforced composites ［J］. High Performance Polymers，2012，24（7）：580-588.
［15］ INOKI M， KIMURA S， DAICHO N， et al. Curing behavior and properties of epoxy resins cured with the diamine having heterocyclic ring ［J］. Journal of Macromolecular Science， Part A：Pure and Applied Chemistry，2002，39（4）：321-331.
［16］ KIM H， YEO H， GOH M， et al. Synthesis and characterization of new diamines containing rigid aromatic ester units as curing agent for high performance epoxy resin ［J］. Macromolecular Research，2017，25（7）：763-766.
［17］ YU X H， CHEN S， XU Y F. Curing kinetics and properties of epoxy resin with 1,4-bis (2,4-diaminophenoxy) benzene ［J］. Journal of Wuhan University of Technology（Materials Science Edition），2018，33（5）：1256-1262.
［18］ PETERSON J J， WERRE M， SIMON Y C， et al. Carborane-containing polyfluorene：o-carborane in the main Chain ［J］. Macromolecules，2009，42（22）：8594-8598.
［19］ MEN X T， CHENG Y， CHEN G， et al. Curing behaviour and thermal properties of epoxy resin cured by aromatic diamine with carborane ［J］. High Performance Polymers，2015，27（4）：497-509.
［20］ HU J H， SHAN J Y， ZHAO J Q， et al. Water resistance and curing kinetics of epoxy resins with a novel curing agent of biphenyl-containing amine synthesized by one-pot method ［J］. Thermochimica Acta，2015，606：58-65.
［21］ YI L， HUANG Z X， CAO Y， et al. Synthesis of a novel spiro phosphorus-nitrogen concerted reactive flame-retardant curing agent and its application in epoxy resin ［J］. Frontiers in Materials，2020，7：293：1-8.
［22］ LOU C H， GU J Y， DI M W， et al. Synthesis and characterization of trichlorophenol-blocked polyaryl polyisocyanate ［J］. Iranian Polymer Journal，2011，20（3）：247-255.
［23］ LEVCHIK S，PIOTROWSKI A，WEIL E，et al. New developments in flame retardancy of epoxy resins ［J］. Polymer Degradation and Stability，2005，88（1）：57-62.
［24］ LI A X，MAO P L，LIANG B. The effect of a novel phosphorus-nitrogen reactive flame retardant curing agent on the performance of epoxy resin ［J］. Journal of Macromolecular Science，Part A：Pure and Applied Chemistry，2019，56（3）：179-188.
［25］ 刘晓丽，梁兵. 磷-氮阻燃固化剂的合成及对环氧树脂性能影响［J］. 精细化工，2018，35（2）：187-193.
［26］ YANG S， HUO S Q， WANG J， et al. A highly fire-safe and smoke-suppressive single-component epoxy resin with switchable curing temperature and rapid curing rate ［J］. Composites Part B： Engineering，2021，207：108601：1-11.
［27］ SATDIVE A， MESTRY S， BORSE P， et al. Phosphorus-and silicon-containing amino curing agent for epoxy resin ［J］. Iranian Polymer Journal，2020，29（5）：433-443.

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[1]梁 恩,彭世琼,唐霞霞,等.改性异佛尔酮二胺固化剂的制备与固化性能研究[J].武汉工程大学学报,2024,46(04):375.[doi:10.19843/j.cnki.CN42-1779/TQ.202311020]
　LIANG En,PENG Shiqiong,TANG Xiaxia,et al.Preparation and curing properties of modifiedisophorone diamine curing agents[J].Journal of Wuhan Institute of Technology,2024,46(03):375.[doi:10.19843/j.cnki.CN42-1779/TQ.202311020]

备注/Memo

备注/Memo:
收稿日期：2021-04-20
基金项目：武汉工程大学第十二届研究生教育创新基金（CX2020151）
作者简介：焦 阳，硕士研究生。E-mail：[email protected]
*通讯作者：吴江渝，博士，教授。E-mail：[email protected]
引文格式：焦阳，骆怡欣，尹吉鑫，等. 胺类环氧树脂固化剂改性研究进展［J］. 武汉工程大学学报，2023，45（3）：251-255，354.

更新日期/Last Update: 2023-07-03