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[1]周旋,陈高峰,龙钰璇,等.掺镍多孔纳米SnO2材料的制备及其气敏性能[J].武汉工程大学学报,2010,(12):73-75.[doi:10.3969/j.issn.1674]
 ZHOU Xuan,CHEN Gao feng,LONG Jun xuan,et al.Preparation of Ni2+ doped SnO2 mesoporous material and their gas sensing studies[J].Journal of Wuhan Institute of Technology,2010,(12):73-75.[doi:10.3969/j.issn.1674]
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掺镍多孔纳米SnO2材料的制备及其气敏性能(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
期数:
2010年12期
页码:
73-75
栏目:
化学与化学工程
出版日期:
2010-12-31

文章信息/Info

Title:
Preparation of Ni2+ doped SnO2 mesoporous
material and their gas sensing studies
文章编号:
16742869(2010)12007303
作者:
周旋陈高峰龙钰璇周寻宋文龙林志东*

武汉工程大学湖北省等离子体化学与新材料重点实验室,湖北 武

汉 430074

Author(s):

ZHOU Xuan CHEN Gaofeng LONG Junxuan ZHOU Xun

SONG Wenlong LIN Zhidong

Provincial Key Laboratory of Plasma Chemistry &

Advanced Materials,
Wuhan Institute of Technology, Wuhan 430074, China

关键词:
多孔纳米SnO2聚乙二醇气敏性能
Keywords:
mesoporous SnO2 powder PEG gas sensitivity
分类号:
TP212
DOI:
10.3969/j.issn.1674
文献标志码:
A
摘要:

以SnCl4·5H2O为原料,聚乙二醇(PEG-1000)作为分散剂,利

用沉淀法制备出SnO2纳米粉体,采用扫描电镜(SEM)和X-射线衍射

(XRD)对其形貌和微观结构进行表征.并以其作为基底材料以离子的

形式掺杂摩尔比为1%的Ni2+作为气敏材料,制作掺杂和未掺杂两种

旁热式气敏元件,测试其对乙醇、甲醇和丙酮的气敏特性.发现在较

低的工作温度下两种元件对三种气体都有较高的敏感性,同时Ni离

子的掺杂对三种气体的灵敏度有不同的影响,对乙醇表现出很好的

选择性.

Abstract:

Nanometer SnO2 powder was prepared by

precipitation using SnCl4·5H2O as raw materials and PEG

—1000 as dispersant, the morphology and microstructure

were characterized by SEM and XRD. The indirect heating

gas sensors were prepared using nanoSnO2 and nano

SnO2 doped by metallic ions Ni2+. Gas sensitivity of the

sensor to ethanol, methanol and Acetone was studied. The

results show that two sensors has high sensitivity to

the three gases. Meanwhile, the Ni addition have

different effect on the gas sensitivity to the three

gases, and good selectivity to ethanol.

参考文献/References:

[1]LIN Z D,CHEN G F,ZHOU X,et al.The gas sensitivity

of nano TiO2SnO2 film doped with Cd(II) ion

[J].Materials Letters,2009,63:22772279.
[2]Arijit Chowdhuri,Sushil Kumar Singh,K Sreenivas,et

al.Contribution of adsorbed oxygen and interfacial space

charge for enhanced response of SnO2 sensors having CuO

catalyst for H2S gas[J].Sensors and Actuators

B,2010,145:155166.
[3]Wang Ding,Hu ping,Xu Jiaqiang,et al.Fast response

chlorine gas sensor based on mesoporous SnO2

[J].Sensors and Actuators B,2009,140:383389.
[4]包南,孙剑,谢晴,等.PEG辅助纳米TiO2的可控制备及其光催化

活性[J].传感技术学报,2006,19(5):23542358.
[5]应皆荣,万春荣,姜长印,等.聚乙二醇对无机盐的胶束增溶作

用及在溶胶配制中的应用[J].功能材料,2001,32(2):118120.
[6]Au nanaoparticledecorated porous SnO2 hollow

spheres: a new model for a chemical sensor[J].J Mater

Chem,2010,20,64536459.

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 WU Xuan jun,YUAN Ji zu,YU Yong fu,et al.Study on the properties of poly(lactic acid)/poly(ethylene glycol) blends[J].Journal of Wuhan Institute of Technology,2009,(12):60.
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备注/Memo

备注/Memo:

收稿日期:20100911基金项目:国家自然科学基

金项目(51072141);湖北省教育厅科学研究计划项目(Q20081503)

作者简介:周旋(1988),男,湖北武汉人.研究方向:纳米材料的制

备与应用.指导老师:林志东,男,教授,博士.研究方向:纳米材料

的制备与应用.

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