以SnCl4·5H2O为原料,聚乙二醇(PEG-1000)作为分散剂,利
用沉淀法制备出SnO2纳米粉体,采用扫描电镜(SEM)和X-射线衍射
(XRD)对其形貌和微观结构进行表征.并以其作为基底材料以离子的
形式掺杂摩尔比为1%的Ni2+作为气敏材料,制作掺杂和未掺杂两种
旁热式气敏元件,测试其对乙醇、甲醇和丙酮的气敏特性.发现在较
低的工作温度下两种元件对三种气体都有较高的敏感性,同时Ni离
子的掺杂对三种气体的灵敏度有不同的影响,对乙醇表现出很好的
选择性.
Nanometer SnO2 powder was prepared by
precipitation using SnCl4·5H2O as raw materials and PEG
—1000 as dispersant, the morphology and microstructure
were characterized by SEM and XRD. The indirect heating
gas sensors were prepared using nanoSnO2 and nano
SnO2 doped by metallic ions Ni2+. Gas sensitivity of the
sensor to ethanol, methanol and Acetone was studied. The
results show that two sensors has high sensitivity to
the three gases. Meanwhile, the Ni addition have
different effect on the gas sensitivity to the three
gases, and good selectivity to ethanol.
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收稿日期:20100911基金项目:国家自然科学基
金项目(51072141);湖北省教育厅科学研究计划项目(Q20081503)
作者简介:周旋(1988),男,湖北武汉人.研究方向:纳米材料的制
备与应用.指导老师:林志东,男,教授,博士.研究方向:纳米材料
的制备与应用.