|本期目录/Table of Contents|

[1]许晨希,朱 丽,王树林,等.无机陶瓷膜在含油废水处理中的应用[J].武汉工程大学学报,2020,42(05):511-517.[doi:10.19843/j.cnki.CN42-1779/TQ.201909030]
 XU Chenxi,ZHU Li,WANG Shulin,et al.Application of Inorganic Ceramic Membrane in Treatment of Oily Wastewater[J].Journal of Wuhan Institute of Technology,2020,42(05):511-517.[doi:10.19843/j.cnki.CN42-1779/TQ.201909030]
点击复制

无机陶瓷膜在含油废水处理中的应用(/HTML)
分享到:

《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
42
期数:
2020年05期
页码:
511-517
栏目:
材料科学与工程
出版日期:
2021-01-29

文章信息/Info

Title:
Application of Inorganic Ceramic Membrane in Treatment of Oily Wastewater
文章编号:
1674 - 2869(2020)05 - 0511 - 07
作者:
许晨希朱 丽王树林季家友陈常连伍梦宇张宏亮徐 慢*
武汉工程大学材料科学与工程学院,湖北 武汉 430205
Author(s):
XU ChenxiZHU LiWANG ShulinJI JiayouCHEN ChanglianWU Mengyu ZHANG Hongliang XU Man*
School of Materials Science and Engineering,Wuhan Institute of Technology,Wuhan 430205,China
关键词:
油水分离无机陶瓷膜膜污染抗污染
Keywords:
oil-in-water emulsion separation inorganic ceramic membrane membrane fouling anti-fouling
分类号:
TB321
DOI:
10.19843/j.cnki.CN42-1779/TQ.201909030
文献标志码:
A
摘要:
综述了在油水分离中减缓膜污染、提高过滤效率的途径,即可以通过优化膜的孔径、膜表面亲水改性、构筑三维网孔结构的新型分离膜以及使用膜清洗等方法提高膜的抗污染性能。研究表明:控制膜孔径略小于油滴直径时能获得较理想的分离效率与较大的渗透通量;SiC陶瓷膜及表面负载Al2O3、TiO2、ZrO2等物质的其他分离膜具有亲水疏油性并且能够提高膜的抗污染性能,可使油滴截留率提高到98%以上,减缓膜污染;利用化学气相沉积技术构筑的CNTs三维网孔状结构膜可使油截留率达到100%;最后,采用化学清洗结合反冲洗可有效恢复陶瓷膜的膜通量。
Abstract:
The methods of alleviating the membrane fouling and improving filtration efficiency in oil/water separation were summarized,such as the improving anti-fouling performance of membrane by optimization of the pore diameter of membrane,the hydrophilic modification of membrane surface,the construction of a novel separation membrane with three-membrane network structure,the membrane cleaning,etc. Studies have indicated that the more ideal separation efficiency and the larger permeation flux can be obtained when the pore diameter of membrane is controlled to be slightly smaller than the diameter of oil droplet. SiC ceramic membrane and other separation membranes with Al2O3,TiO2,ZrO2,etc. on the surface possess the hydrophilic and oleophobic properties and can improve the anti-fouling property of membrane,which can increase the oil rejection rate to more than 98% and alleviate membrane fouling. The oil rejection rate can reach 100% by using CNTs membrane with three-membrane network constructed by chemical vapour deposition technique. Finally,the membrane flux of ceramic membrane can be effectively restored with chemical cleaning combined with backwashing.

参考文献/References:

[1] 张雪芳. 膜法油水分离中乳化剂影响机理研究[D]. 大连:大连理工大学,2018. [2] 张攀,尤朝阳,秦海燕,等. MBR深度处理石化含油废水研究进展 [J]. 水处理技术,2016,42(5):5-7,16. [3] EBRAHIMI M,WILLERSHAUSEN D,ASHAGHI K S,et al. Investigations on the use of different ceramic membranes for efficient oil-field produced water treatment [J]. Desalination,2010,250(3):991-996. [4] 王雪,徐佳,蒋钰烨,等. 超滤膜处理乳化油废水的研究进展 [J]. 现代化工,2011,31(6):28-31. [5] 王建芳,赵庆良,林佶侃,等. 生物强化技术及其在废水生物处理中的应用 [J]. 环境工程学报,2007,1(9):40-45. [6] J·鲁比奥,崔洪山,李长根. 作为废水处理技术中的浮选法 [J]. 国外金属矿选矿,2002(6):4-13. [7] 聂文博,郭敏,李林霜,等. 高氟水处理吸附剂的研究进展 [J]. 广州化工,2015,43(20):1-6,35. [8] SAMAEI S M,GATO-TRINIDAD S, ALTAEE A. The application of pressure-driven ceramic membrane technology for the treatment of industrial wastewaters: a review[J]. Separation and Purification Technology,2018,200:198-220. [9] ZHU Y Z,WANG D,JIANG L,et al. Recent progress in developing advanced membranes for emulsified oil/water separation [J]. NPG Asia Materials,2014,6:e101:1-11. [10] 任秀娥,李刚,陈建标,等. 面向油水分离的无机膜制备及应用进展 [J]. 化工进展,2018,37(10):3928-3935. [11] 孙颖. 膜分离材料在含油废水处理中的研究进展 [J]. 广东化工,2018,45(8):176-177. [12] 范益群,漆虹,徐南平. 多孔陶瓷膜制备技术研究进展 [J]. 化工学报,2013,64(1):107-115. [13] 范会生,陆阿定,张海春,等. 陶瓷膜处理储运油泥废水实验研究 [J]. 广东化工,2017,44(10):49-50,65. [14] 胡学兵,周健儿,汪永清,等. 平均孔径与改性氧化物对α-Al2O3微滤膜油水分离效率的影响 [J]. 硅酸盐学报,2010,38(10):1900-1904. [15] FUKUSHIMA M,ZHOU Y,YOSHIZAWA Y I. Fabrication and microstructural characterization of porous SiC membrane supports with Al2O3-Y2O3 additives [J]. Journal of Membrane Science,2009,339(1/2):78-84. [16] 王春梅,谷和平,王义刚,等. 陶瓷微滤膜处理含油废水的工艺研究 [J]. 南京化工大学学报(自然科学版),2000,22(5):38-42. [17] 张大为,米世超,付超,等. 纤维素/陶瓷复合膜的制备及油水分离性能研究 [J]. 表面技术,2017,46(11):22-28. [18] CHANG Q B, ZHOU J E, WANG Y Q, et al. Hydrophilic modification of Al2O3 microfiltration membrane with nano-sized γ-Al2O3 coating [J]. Desalination,2010,262(1/2/3):110-114. [19] YANG C,ZHANG G S,XU N P,et al. Preparation and application in oil-water separation of ZrO2/α-Al2O3 MF membrane [J]. Journal of Membrane Science,1998,142(2):235-243. [20] 周健儿,包启富,汪永清,等. 无机陶瓷膜在含油废水中的应用进展 [J]. 陶瓷学报,2008,29(1):54-57. [21] 孔令刚. 无机陶瓷超滤膜处理乳化油的工程实例 [J]. 资源节约与环保,2017(8):12-13. [22] 王永红. 新型陶瓷分离膜制备科学基础和性能研究[D]. 合肥:中国科学技术大学,2006. [23] YANG G C C,LI C J. Tubular TiO2/Al2O3 composite membranes:preparation,characterization,and perfor- mance in electrofiltration of oxide-CMP wastewater [J]. Desalination,2008,234(1/2/3):354-361. [24] ZHU L,CHEN M L,DONG Y C,et al. A low-cost mullite-titania composite ceramic hollow fiber microfiltration membrane for highly efficient separation of oil-in-water emulsion [J]. Water Research,2016,90:277-285. [25] 袁静,廖芳芳,郭雅妮,等. 超亲水超疏油油水分离膜的制备及其性能 [J]. 化学进展,2019,31(1):144-155. [26] 章畅,王巧英,吴志超. 亲水/水下超疏油的油水分离膜的制备及性能 [J]. 净水技术,2019,38(2):86-92. [27] DE WIT P,KAPPERT E J,LOHAUS T,et al. Highly permeable and mechanically robust silicon carbide hollow fiber membranes [J]. Journal of Membrane Science,2015,475:480-487. [28] 叶世威,王贝辉,洪昱斌,等. 碳化硅陶瓷膜在油水分离中的应用研究 [J]. 功能材料,2011,42(2):248-251. [29] 徐南平,邢卫红,王沛. 无机膜在工业废水处理中的应用与展望 [J]. 膜科学与技术,2000,20(3):23-28. [30] ZHU L,DONG X F,XU M,et al. Fabrication of mullite ceramic-supported carbon nanotube composite membranes with enhanced performance in direct separation of high-temperature emulsified oil droplets [J]. Journal of Membrane Science,2019,582:140-150. [31] CHEN X W,HONG L,XU Y F,et al. Ceramic pore channels with inducted carbon nanotubes for removing oil from water [J]. ACS Applied Materials & Interfaces,2012,4(4):1909-1918. [32] ARORA R,BALASUBRAMANIAN K. Hierarchically porous PVDF/nano-SiC foam for distant oil-spill cleanups [J]. RSC Advances,2014,4(96):53761- 53767. [33] ABADI S R H, SEBZARI M R, HEMATI M, et al. Ceramic membrane performance in microfiltration of oily wastewater [J]. Desalination,2011,265(1/2/3):222-228. [34] 吴桢,金江,陈悦,等. 无机膜处理机加工含油废冷却液研究 [J]. 中国给水排水,2001,17(6):73-76. [35] 代小元,沈凡,戴武斌,等. 碳化硅陶瓷膜处理工业废水的工艺特性研究 [J]. 武汉工程大学学报,2018,40(3):284-287. [36] MOENE R,MAKKEE M,MOULIJN J A. High surface area silicon carbide as catalyst support characterization and stability [J]. Applied Catalysis A:General,1998,167(2):321-330.

相似文献/References:

[1]鲍世轩,华 乐,文 轩,等.苯乙烯-马来酸酐共聚物静电纺丝膜的制备与油水分离性能[J].武汉工程大学学报,2019,(03):258.[doi:10. 3969/j. issn. 1674-2869. 2019. 03. 010]
 BAO Shixuan,HUA Le,WEN Xuan,et al.Preparation and Oil-Water Separation of Poly (Styrene-Co-Maleic Anhydride) Electrospinning Film[J].Journal of Wuhan Institute of Technology,2019,(05):258.[doi:10. 3969/j. issn. 1674-2869. 2019. 03. 010]
[2]郭晓航,胡鹏涛,田 驰,等.PVA/PVP/SiO2复合膜过滤器的制备及油水分离性能[J].武汉工程大学学报,2023,45(02):181.[doi:10.19843/j.cnki.CN42-1779/TQ.202201002]
 GUO Xiaohang,HU Pengtao,TIAN Chi,et al.Preparation and Oil-Water Separation Performance ofPVA/PVP/SiO2 Composite Membrane Filter[J].Journal of Wuhan Institute of Technology,2023,45(05):181.[doi:10.19843/j.cnki.CN42-1779/TQ.202201002]
[3]祝博萱,田雪凡,周 婷,等.Fe3O4/聚苯乙烯改性密胺海绵的制备及其吸油性能[J].武汉工程大学学报,2024,46(05):522.[doi:10.19843/j.cnki.CN42-1779/TQ.202208003]
 ZHU Boxuan,TIAN Xuefan,ZHOU Ting,et al.Preparation and oil absorption capacity of Fe3O4/polystyrene-modified melamine sponge[J].Journal of Wuhan Institute of Technology,2024,46(05):522.[doi:10.19843/j.cnki.CN42-1779/TQ.202208003]

备注/Memo

备注/Memo:
收稿日期:2019-09-24基金项目:湖北省技术创新专项(2016ACA161);武汉工程大学博士启动基金(18QD06);武汉工程大学第十届研究生教育创新基金(CX2018056)作者简介:许晨希,硕士研究生。E-mail:[email protected]*通讯作者:徐 慢,博士,教授。E-mail:[email protected]引文格式:许晨希,朱丽,王树林,等. 无机陶瓷膜在含油废水处理中的应用[J]. 武汉工程大学学报,2020,42(5):511-517.
更新日期/Last Update: 2020-10-30