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[1]田宇航,战胜祺,周明钰,等.CEOs/HNTs/PBAT复合薄膜的制备及其性能研究[J].武汉工程大学学报,2024,46(04):390-397.[doi:10.19843/j.cnki.CN42-1779/TQ.202311007]
　TIAN Yuhang,ZHAN Shengqi,ZHOU Mingyu,et al.Preparation and properties of CEOs/HNTs/PBAT composite films[J].Journal of Wuhan Institute of Technology,2024,46(04):390-397.[doi:10.19843/j.cnki.CN42-1779/TQ.202311007]
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CEOs/HNTs/PBAT复合薄膜的制备及其性能研究(/HTML)
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《武汉工程大学学报》[ISSN:1674-2869/CN:42-1779/TQ]

卷:
46
期数:
2024年04期
页码:
390-397
栏目:
材料科学与工程
出版日期:
2024-08-28

文章信息/Info

Title:
Preparation and properties of CEOs/HNTs/PBAT composite films
文章编号:
1674 - 2869（2024）04 - 0390 - 08
作者:
田宇航; 战胜祺; 周明钰; 雷若兰; 郑华明*
武汉工程大学材料科学与工程学院，湖北 武汉 430205
Author(s):
TIAN Yuhang; ZHAN Shengqi; ZHOU Mingyu; LEI Ruolan; ZHENG Huaming*
School of Materials Science and Engineering，Wuhan Institute of Technology，Wuhan 430205，China
关键词:
肉桂精油; 埃洛石纳米管; 纳米粒子; 复合薄膜
Keywords:
cinnamon essential oils;  halloysite nanotubes;  nanoparticles;  composite films
分类号:
TB383.2
DOI:
10.19843/j.cnki.CN42-1779/TQ.202311007
文献标志码:
A
摘要:
为了延长食品的货架期和减少白色污染，利用埃洛石纳米管（HNTs）负载肉桂精油（CEOs）得到CEOs/HNTs纳米粒子。将其添加到聚己二酸/对苯二甲酸丁二醇酯（PBAT）树脂中，进行熔融共混挤出，制备出具有抗菌效果的复合薄膜。热重分析表明HNTs对CEOs的初始负载率约为10%；场发射扫描电子显微镜显示HNTs长度为500~1 500 nm，直径为50~100 nm，CEOs/HNTs纳米粒子均匀地分散在PBAT薄膜中。与PBAT薄膜相比，CEOs/HNTs/PBAT复合薄膜的力学性能得到提高，透光和透水等物理性能在一定程度上得到改善。对金黄色葡萄球菌和大肠杆菌的抗菌效果可以达到93%和97%。同时在对草莓的保鲜试验中，取得了很好的保鲜效果。
Abstract:
To prolong the shelf life of food and reduce plastic pollution，halloysite nanotubes were loaded with cinnamon essential oils（CEOs/HNTs）. Then，the CEOs/HNTs were added to poly(butyleneadipate-co-terephthalate) （PBAT） resin and melted，blended and extruded to prepare composite films with antibacterial effects. Thermogravimetric analysis shows that the loading rate of the halloysite nanotubes is about 10%. The results of field emission scanning electron microscope indicate the length of the HNTs is 500-1 500 nm and the diameter is 50-100 nm. Also，CEOs/HNTs nanoparticles are evenly distributed in the PBAT resin. Compared with PBAT films，the mechanical properties of CEOs/HNTs/PBAT composite films are improved，and the physical properties such as light and water transmission are improved to a certain extent. The antibacterial activity against Staphylococcus aureus and Escherichia coli reached 93% and 97%，respectively. At the same time，a good freshness-keeping effect was obtained in the freshness-keeping experiment of strawberry.

参考文献/References:

［1］ VAHEDIKIA N，GARAVAND F，TAJEDDIN B，et al. Biodegradable zein film composites reinforced with chitosan nanoparticles and cinnamon essential oil：physical，mechanical，structural and antimicrobial attributes ［J］. Colloids and Surfaces B：Biointerfaces，2019，177：25-32.

［2］ HASANIN M S，YOUSSEF A M. Ecofriendly bioactive film doped CuO nanoparticles based biopolymers and reinforced by enzymatically modified nanocellulose fibers for active packaging applications ［J］. Food Packaging and Shelf Life，2022，34：100979.
［3］ 白娟，周兴平，解孝林. 微晶纤维素对两步拉伸挤出的PBAT/TPS共混材料的结构与性能的影响［J］.武汉工程大学学报，2022，44（5）：522-527，533.
［4］ WANG Y N，YANG H C，LI B J，et al. Poly(butylene adipate/terephthalate-co-glycolate) copolyester synthesis based on methyl glycolate with improved barrier properties：from synthesis to structure-property ［J］. International Journal of Molecular Sciences，2022，23（19）：11074.
［5］ HUANG T Q， QIAN Y S，WEI J，et al. Polymeric antimicrobial food packaging and its applications ［J］. Polymers，2019，11（3）：560.
［6］ 郑华明，王江丽，田宇航，等. pH驱动法负载香芹酚纳米颗粒的制备及性能［J］.高分子材料科学与工程，2022，38（8）：177-184.
［7］ TOSUN M N，TAYLAN G，DEMIREL ZORBA N N. Antibacterial and antibiofilm activities of some plant essential oils and synergistic effects of cinnamon essential oil with vancomycin against Clostridioides difficile：in vitro study ［J］. Letters in Applied Microbiology，2022，75（3）：598-606.
［8］ 余春平，袁明. 肉桂醛的研究与应用进展［J］.山东化工，2022，51（19）：97-99.
［9］ CHUESIANG P，SANGUANDEEKUL R，SIRIPATRAWAN U. Enhancing effect of nanoemulsion on antimicrobial activity of cinnamon essential oil against foodborne pathogens in refrigerated Asian seabass （Lates calcarifer） fillets ［J］. Food Control，2021，122：107782.
［10］ LIU Q，GAO Y，FU X，et al. Preparation of peppermint oil nanoemulsions：investigation of stability，antibacterial mechanism and apoptosis effects ［J］. Colloids and Surfaces B：Biointerfaces，2021，201：111626.
［11］ ZHENG H M，MEI J，LIU F J，et al. Preparation and characterization of carvacrol essential oil-loaded halloysite nanotubes and their application in antibacterial packaging ［J］. Food Packaging and Shelf Life，2022，34：100972.
［12］ ROZHINA E， BATASHEVA S， MIFTAKHOVA R，et al. Comparative cytotoxicity of kaolinite，halloysite，multiwalled carbon nanotubes and graphene oxide ［J］. Applied Clay Science，2021，205：106041.
［13］ DEB A K，BISWAS B，NAIDU R，et al. Mechanistic insights of hexavalent chromium remediation by halloysite-supported copper nanoclusters ［J］. Journal of Hazardous Materials，2022，421：126812.
［14］ 梅军，王江丽，白越，等. 埃洛石纳米管负载香芹酚及其性能的研究［J］.包装与食品机械，2022，40（2）：56-63.
［15］ 郝明正，乔嘉欣，吕钊霞，等. 用埃洛石负载氨基磺酸胍制备阻燃丁腈橡胶［J］.合成橡胶工业，2021，44（1）：47-50.
［16］ ZHENG H M，WANG J L，YOU F，et al. Fabrication，characterization，and antimicrobial activity of carvacrol-loaded zein nanoparticles using the pH-driven method ［J］. International Journal of Molecular Sciences，2022，23（16）：9227.
［17］ SHI W W， YAN R X， HUANG L Q. Preparation and insecticidal performance of sustained-release cinnamon essential oil microemulsion ［J］. Journal of the Science of Food and Agriculture，2022，102（4）：1397-1404.
［18］ OU T，WU Y H，HAN W X，et al. Synthesis of thickness-controllable polydopamine modified halloysite nanotubes （HNTs@PDA） for uranium(VI)removal ［J］. Journal of Hazardous Materials，2022，424（Part A）：127208.
［19］ PUMCHAN A， CHEYCHAROEN O， UNAJAK S，et al. An oral biologics carrier from modified halloysite nanotubes ［J］. New Journal of Chemistry，2021，45（20）：9130-9136.
［20］ ZHANG Y M，LI Y Q，ZHANG Y F，et al. Thermal behavior and kinetic analysis of halloysite-stearic acid complex ［J］. Journal of Thermal Analysis and Calorimetry，2019，135（4）：2429-2436.
［21］SHAHIDI NOGHABI M，MOLAVEISI M. Microencapsulation optimization of cinnamon essential oil in the matrices of gum Arabic，maltodextrin，and inulin by spray-drying using mixture design ［J］. Journal of Food Process Engineering，2020，43（2）：e13341.
［22］ KLINMALAI P，SRISA A，LAORENZA Y，et al. Antifungal and plasticization effects of carvacrol in biodegradable poly (lactic acid) and poly(butylene adipate terephthalate) blend films for bakery packaging ［J］. LWT，2021，152：112356.
［23］ JELI? A， MARINKOVI? A， SEKULI? M， et al. Design of halloysite modification for improvement of mechanical properties of the epoxy based nanocomposites ［J］. Polymer Composites，2021，42（5）：2180-2192.
［24］ TORNUK F， SAGDIC O， HANCER M， et al. Development of LLDPE based active nanocomposite films with nanoclays impregnated with volatile compounds ［J］. Food Research International，2018，107：337-345.
［25］ LAORENZA Y，HARNKARNSUJARIT N. Carvacrol，citral and α-terpineol essential oil incorporated biodegradable films for functional active packaging of Pacific white shrimp ［J］. Food Chemistry，2021，363：130252.
［26］ AHAMAD A，KUMAR P. Evaluation of mechanical，thermal，and morphological properties of PEEK/PEI matrix reinforced with halloysite nanotubes ［J］. Polymer-Plastics Technology and Materials，2021，60（14）：1557-1567.
［27］ AHMED J，MULLA M，JACOB H，et al. Polylactide/poly (ε-caprolactone) /zinc oxide/clove essential oil composite antimicrobial films for scrambled egg packaging ［J］. Food Packaging and Shelf Life，2019，21：100355.
［28］ BAGDE P， NADANATHANGAM V. Mechanical，antibacterial and biodegradable properties of starch film containing bacteriocin immobilized crystalline nanocellulose ［J］. Carbohydrate Polymers，2019，222：115021.
［29］ BASIAK E，LENART A，DEBEAUFORT F. Effect of starch type on the physico-chemical properties of edible films ［J］. International Journal of Biological Macromolecules，2017，98：348-356.

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备注/Memo

备注/Memo:
收稿日期：2023-11-14
基金项目：武汉工程大学第十四届研究生教育创新基金（CX2022224）
作者简介：田宇航，硕士研究生。Email：[email protected]
*通信作者：郑华明，博士，教授。Email：[email protected]
引文格式：田宇航，战胜祺，周明钰，等. CEOs/HNTs/PBAT复合薄膜的制备及其性能研究［J］. 武汉工程大学学报，2024，46（4）：390-397.
更新日期/Last Update: 2024-08-31